| dc.contributor |
Randall Laboratory of Physics, University of Michigan, Ann Arbor, Michigan, USA |
|
| dc.contributor |
The B. F. Goodrich Company, Research Center, Brecksville, Ohio, USA |
|
| dc.contributor |
The B. F. Goodrich Company, Research Center, Brecksville, Ohio, USA |
|
| dc.creator |
Shipman, J. J. |
|
| dc.creator |
Folt, V. L. |
|
| dc.creator |
Krimm, Samuel |
|
| dc.date |
2006-04-13T14:56:37Z |
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| dc.date |
2006-04-13T14:56:37Z |
|
| dc.date |
1962 |
|
| dc.date.accessioned |
2022-05-19T13:30:21Z |
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| dc.date.available |
2022-05-19T13:30:21Z |
|
| dc.identifier |
Shipman, J.J., Folt, V.L., Krimm, S. (1962)."Characteristic infrared frequencies of rotational isomers of alkyl chlorides." Spectrochimica Acta 18(4): 1603-1613. <http://hdl.handle.net/2027.42/32341> |
|
| dc.identifier |
http://www.sciencedirect.com/science/article/B6W98-4FW6JX5-3J/2/297296078be9c556126a8cb9793203dd |
|
| dc.identifier |
http://hdl.handle.net/2027.42/32341 |
|
| dc.identifier |
Spectrochimica Acta |
|
| dc.identifier.uri |
http://localhost:8080/xmlui/handle/CUHPOERS/117349 |
|
| dc.description |
A study of the infrared spectra of primary, secondary and tertiary alkyl chlorides reveals that the frequency of the so-called C-Cl stretching mode is a function of the detailed structure in the vicinity of the C-Cl bond. In primary chlorides the frequency region depends on whether a hydrogen atom or a carbon atom is irons to the Cl atom across the common C-C bond. In secondary chlorides it is found that the trans substituents on both C-C bonds adjacent to the C-Cl bond are important in determining the frequency region, and a similar result is observed for the tertiary chlorides. Frequency ranges for the various rotationally isomeric structures of primary, secondary and tertiary chlorides are given. |
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| dc.description |
Peer Reviewed |
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| dc.description |
http://deepblue.lib.umich.edu/bitstream/2027.42/32341/1/0000411.pdf |
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| dc.format |
2378841 bytes |
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| dc.format |
3118 bytes |
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| dc.format |
application/pdf |
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| dc.format |
text/plain |
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| dc.format |
application/pdf |
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| dc.language |
en_US |
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| dc.publisher |
Elsevier |
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| dc.rights |
IndexNoFollow |
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| dc.subject |
Materials Science and Engineering |
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| dc.subject |
Chemistry |
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| dc.subject |
Chemical Engineering |
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| dc.subject |
Biological Chemistry |
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| dc.subject |
Engineering |
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| dc.subject |
Science |
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| dc.subject |
Health Sciences |
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| dc.title |
Characteristic infrared frequencies of rotational isomers of alkyl chlorides |
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| dc.type |
Article |
|