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Low temperature hot corrosion screening of single crystal superalloys

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dc.creator Smialek, James L.
dc.creator Gray, Simon
dc.date 2018-10-26T14:23:46Z
dc.date 2018-10-26T14:23:46Z
dc.date 2018-10-25
dc.date.accessioned 2022-05-25T16:39:22Z
dc.date.available 2022-05-25T16:39:22Z
dc.identifier James L. Smialek and Simon Gray. Low temperature hot corrosion screening of single crystal superalloys. Materials, 2018, Volume 11, Issue 11, Article number 2098
dc.identifier 1996-1944
dc.identifier https://doi.org/10.3390/ma11112098
dc.identifier http://dspace.lib.cranfield.ac.uk/handle/1826/13584
dc.identifier.uri http://localhost:8080/xmlui/handle/CUHPOERS/182439
dc.description Single crystal superalloys were screened in Type II molten (Na,K)-sulfate hot corrosion re-coat tests in air +300 ppm SO2 at 700 °C. They exhibited large 20–40 mg/cm2 weight changes, repeated spallation, and non-protective, 25–50 μm thick corrosion layers after 300 h of testing. Scale cross sections revealed dual outer Ni(Co)O and inner Al(Cr)S-rich corrosion layers. This chemical differentiation was partially consistent with previous models of oxide fluxing, alloy sulfidation, NiO micro-channel diffusion, and synergistic dissolution mechanisms. Broad shallow pits or uniform attack morphologies were consistent with prior studies performed in high >100 ppm pSO2 environments. Higher Mo experimental alloys trended toward more degradation, producing 100 μm thick scales with distinct Al(Cr)S-rich inner layers or 500 μm thick NiO. The aggressive behavior in these environments supports the need for LTHC-resistant coatings for single crystal superalloys.
dc.language en
dc.publisher MDPI
dc.rights Attribution 4.0 International
dc.rights http://creativecommons.org/licenses/by/4.0/
dc.subject Type II hot corrosion
dc.subject single crystal superalloys
dc.subject molten salt
dc.title Low temperature hot corrosion screening of single crystal superalloys
dc.type Article


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