The folder contains raw NMR spectra of 3-fluoro-3-deoxy-D-glucose, which were acquired using Bruker NMR spectrometers using a range of NMR experiments. Dataset is the subject of RSC Advances article entitled 19F-centred NMR analysis of mono-fluorinated compounds. Specific files are as follows (also listed in summary word document): 1. 400 MHz 1H spectrum of 3-fluoro-3-deoxy-D-glucose, 1. 2. 400 MHz 1H coupled 1D 19F spectrum of 1. 3. 19F-detected z-filtered 2D 1H, 19F HETCOR spectrum of 1. 4. 2D 1H, 19F TOCSY-HETCOR spectrum of 1. 5. 2D 19F, 1H CP-DIPSI3-DIPSI2 spectrum of 1 with FH transfer only. 6. 2D 19F, 1H CP-DIPSI3-DIPSI2 spectrum of 1 with additional HH transfer. 7. 2D 19F, 13C HMBC spectrum optimised for nJFC correlations 8. (3,2)D H1CnF correlation spectrum of 1 9. In phase (3,2)D H1CnF correlation spectrum of 1 10. Antiphase (3,2)D H1CnF correlation spectrum of 11. 400 MHz 1H spectrum of 3-fluoro-3-deoxy-D-glucose, 1. 2. 400 MHz 1H coupled 1D 19F spectrum of 1. 3. 19F-detected z-filtered 2D 1H, 19F HETCOR spectrum of 1. 4. 2D 1H, 19F TOCSY-HETCOR spectrum of 1. 5. 2D 19F, 1H CP-DIPSI3-DIPSI2 spectrum of 1 with FH transfer only. 6. 2D 19F, 1H CP-DIPSI3-DIPSI2 spectrum of 1 with additional HH transfer. 7. 2D 19F, 13C HMBC spectrum optimised for nJFC correlations 8. (3,2)D H1CnF correlation spectrum of 1 9. In phase (3,2)D H1CnF correlation spectrum of 1 10. Antiphase (3,2)D H1CnF correlation spectrum of 1