| dc.contributor |
Judd, Chris J. |
|
| dc.contributor |
Champness, Neil R. |
|
| dc.creator |
Saywell, Alex |
|
| dc.date |
2019-04-25T12:42:03Z |
|
| dc.date |
2019-04-25T12:42:03Z |
|
| dc.date |
2019-04-25 |
|
| dc.identifier |
https://rdmc.nottingham.ac.uk/handle/internal/335 |
|
| dc.identifier |
http://doi.org/10.17639/nott.331 |
|
| dc.description |
On-surface reactions based on metal-catalysed Ullmann coupling have been successfully employed to synthesise a wide variety of covalently coupled structures. Substrate chemistry and topology are both known to effect the progression of an on-surface reaction; offering routes to control efficiency and selectivity. Here, we detail ultra-high vacuum scanning probe microscopy experiments showing that templating a catalytically active surface, via a supramolecular template, influences the reaction pathway of an on-surface Ullmann-type coupling reaction by inhibiting one potential intermediate structure and stabilising another. |
|
| dc.language |
en |
|
| dc.publisher |
The University of Nottingham |
|
| dc.relation |
https://doi.org/10.1002/chem.201704693 |
|
| dc.subject |
Heterogeneous catalysis |
|
| dc.subject |
Scanning probe microscopy |
|
| dc.subject |
Supramolecular chemistry |
|
| dc.subject |
Surface chemistry |
|
| dc.subject |
heterogeneous catalysis, supramolecular chemistry, scanning probe microscopy, surface chemistry, templated reactions |
|
| dc.subject |
Physical sciences::Chemistry::Physical chemistry |
|
| dc.subject |
Physical sciences::Physics::Chemical physics, Solid-state physics |
|
| dc.subject |
Q Science::QD Chemistry::QD450 Physical and theoretical chemistry |
|
| dc.title |
An on-surface reaction confined within a porous molecular template |
|
| dc.type |
dataset |
|