Sangam: A Confluence of Knowledge Streams

Synthesis, Characterization, and Non-Covalent Interactions of Palladium(II)-Amino Acid Complexes

Show simple item record

dc.contributor Chemistry
dc.creator Hobart, David B. Jr.
dc.creator Berg, Michael A. G.
dc.creator Rogers, Hannah M.
dc.creator Merola, Joseph S.
dc.date 2021-07-23T17:28:29Z
dc.date 2021-07-23T17:28:29Z
dc.date 2021-07-17
dc.date 2021-07-23T13:27:26Z
dc.date.accessioned 2023-03-01T18:53:08Z
dc.date.available 2023-03-01T18:53:08Z
dc.identifier Hobart, D.B., Jr.; Berg, M.A.G.; Rogers, H.M.; Merola, J.S. Synthesis, Characterization, and Non-Covalent Interactions of Palladium(II)-Amino Acid Complexes. Molecules 2021, 26, 4331.
dc.identifier http://hdl.handle.net/10919/104377
dc.identifier https://doi.org/10.3390/molecules26144331
dc.identifier.uri http://localhost:8080/xmlui/handle/CUHPOERS/281691
dc.description The reaction of palladium(II) acetate with acyclic amino acids in acetone/water yields square planar bis-chelated palladium amino acid complexes that exhibit interesting non-covalent interactions. In all cases, complexes were examined by multiple spectroscopic techniques, especially HRMS (high resolution mass spectrometry), IR (infrared spectroscopy), and <sup>1</sup>H NMR (nuclear magnetic resonance) spectroscopy. In some cases, suitable crystals for single crystal X-ray diffraction were able to be grown and the molecular structure was obtained. The molecular geometries of the products are discussed. Except for the alanine complex, all complexes incorporate water molecules into the extended lattice and exhibit N-H···O and/or O···(HOH)···O hydrogen bonding interactions. The non-covalent interactions are discussed in terms of the extended lattice structures exhibited by the structures.
dc.description Published version
dc.format application/pdf
dc.format application/pdf
dc.language en
dc.publisher MDPI
dc.rights Creative Commons Attribution 4.0 International
dc.rights http://creativecommons.org/licenses/by/4.0/
dc.subject palladium
dc.subject chelate
dc.subject amino acid
dc.subject hydrogen bonding
dc.subject non-covalent interaction
dc.subject X-ray crystallography
dc.title Synthesis, Characterization, and Non-Covalent Interactions of Palladium(II)-Amino Acid Complexes
dc.title Molecules
dc.type Article - Refereed
dc.type Text


Files in this item

Files Size Format View
molecules-26-04331-v3.pdf 10.87Mb application/pdf View/Open

This item appears in the following Collection(s)

Show simple item record

Search DSpace


Advanced Search

Browse